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Legi și ecuații fizice: Dinamica fluidelor și termodinamică

Ghid de referință complet pentru 21 de legi fizice și ecuații fundamentale în dinamica fluidelor și termodinamică: mecanica fluidelor, principiile termodinamicii și transferul termic.

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Fluid dynamics and thermal physics are foundational theoretical pillars of aerospace engineering, propulsion systems, energy conversion, chemical processing, and microelectronic thermal management. From the macroscopic continuity and momentum conservation of fluid streams to the microscopic statistical distributions and thermodynamic limits of molecular heat motion, physical equations construct a rigorous analytical framework.

This cheat sheet systematically organizes 21 core physical laws and foundational equations in fluid dynamics and thermal physics, partitioned into Fluid Dynamics, Laws of Thermodynamics, Kinetic Theory & Statistical Physics, and Thermal Radiation & Heat Transfer, presenting standard mathematical formulas, key variable definitions, physical principles, validity domains, and industrial applications.

🔗 Matricea legilor și ecuațiilor fizice: Mecanică clasică · Dinamica fluidelor și termodinamică · Electromagnetism · Optică și acustică · Mecanică cuantică · Relativitate și cosmologie · Fizică nucleară și a particulelor · Astrofizică și geofizică

1. Fluid Dynamics (7 Laws)

Fluid dynamics describes the conservation of mass, momentum transfer, energy conversion, and pressure response mechanisms of fluids in static and flowing states.

01 · Continuity Equation Continuity Equation (Conservation of Mass)
Fluid Mechanics Foundation
$$A_1 v_1 = A_2 v_2 \iff \rho_1 A_1 v_1 = \rho_2 A_2 v_2$$
  • ①Esență fizică: Law of conservation of mass in steady fluid flow; fluid velocity increases where a conduit constricts and decreases where it widens.
  • ②Definirea variabilelor: $A$ is conduit cross-sectional area ($\text{m}^2$), $v$ is area-averaged flow velocity ($\text{m/s}$), and $\rho$ is fluid density ($\text{kg/m}^3$). For incompressible flow ($\rho = \text{const}$), volumetric flow rate $Q = Av$ is conserved.
  • ③Semnificație fundamentală: The primary constraint equation for piping and streamtube analysis, representing the 1D integral form of $\nabla\cdot(\rho \mathbf{v}) + \partial\rho/\partial t = 0$.
  • ④Domeniu de validitate și aplicații: Incompressible assumption holds for liquids and low-speed gas flows (Mach number $\text{Ma} < 0.3$); high-speed compressible flows require density-varying mass flux. Applied in hydraulic piping, firefighting hose nozzles, and river canyon torrent dynamics.
02 · Bernoulli's Equation Bernoulli's Principle
1738 · Daniel Bernoulli (Switzerland)
$$p + \rho g h + \frac{1}{2}\rho v^2 = \text{const}$$
  • ①Esență fizică: Conservation of mechanical energy along a streamline in steady, inviscid, incompressible flow; regions of higher flow speed experience lower static pressure, and vice versa.
  • ②Definirea variabilelor: $p$ is static pressure ($\text{Pa}$), $\rho$ is density, $g$ is gravitational acceleration, $h$ is geometric elevation, $v$ is flow speed, and $\frac{1}{2}\rho v^2$ is dynamic pressure.
  • ③Semnificație fundamentală: The foundational baseline of low-speed aerodynamics and hydrodynamics, illustrating lossless exchange among pressure potential, gravitational potential, and kinetic energy.
  • ④Domeniu de validitate și aplicații: Strictly valid along a single streamline in inviscid, steady, incompressible flow; real viscous fluids suffer irreversible total head loss. Applied in airfoil aerodynamic lift generation, Venturi flowmeters, Pitot tube airspeed indicators, and atomizers.
03 · Pascal's Law Pascal's Principle
1653 · Blaise Pascal (France)
$$\Delta p = \text{const} \iff \frac{F_1}{A_1} = \frac{F_2}{A_2}$$
  • ①Esență fizică: Any pressure increment applied to an enclosed incompressible fluid is transmitted undiminished in all directions throughout the entire fluid and onto the container walls.
  • ②Definirea variabilelor: $\Delta p$ is pressure change, $F_1, F_2$ are applied forces on respective pistons, and $A_1, A_2$ are the corresponding piston surface areas.
  • ③Semnificație fundamentală: The axiomatic foundation of fluid power transmission and hydraulics, enabling substantial mechanical force multiplication proportional to area ratio.
  • ④Domeniu de validitate și aplicații: Static, enclosed, incompressible liquids. Applied in automotive hydraulic brake systems, industrial hydraulic presses, bottle jacks, heavy excavator arms, and aircraft flight control surface actuators.
04 · Archimedes' Principle Buoyancy Principle
c. 250 BCE · Archimedes (Ancient Greece)
$$F_b = \rho g V_{\text{disp}}$$
  • ①Esență fizică: Any object immersed in a static fluid experiences a vertically upward buoyant force equal in magnitude to the weight of the fluid displaced by the object. Microscopically arises from the hydrostatic pressure differential between bottom and top surfaces.
  • ②Definirea variabilelor: $F_b$ is buoyant force ($\text{N}$), $\rho$ is ambient fluid density ($\text{kg/m}^3$), $g$ is gravitational acceleration, and $V_{\text{disp}}$ is displaced fluid volume ($\text{m}^3$).
  • ③Semnificație fundamentală: The definitive principle governing static equilibrium of floating and submerged bodies, fluid density metrology, and naval hydrostatics.
  • ④Domeniu de validitate și aplicații: Static or uniformly moving immersed bodies. Floats when mean body density is less than fluid density, neutral at equal density, sinks when denser. Applied in ship displacement engineering, submarine ballast tank diving control, hot air balloon buoyancy, and hydrometer density readings.
05 · Poiseuille's Law Hagen-Poiseuille Equation
1840 · Jean Léonard Marie Poiseuille (France)
$$Q = \frac{\pi r^4 \Delta p}{8 \eta L}$$
  • ①Esență fizică: In steady laminar flow of a viscous fluid through a cylindrical pipe, volumetric flow rate is directly proportional to the driving pressure gradient and the fourth power of pipe radius ($r^4$), and inversely proportional to fluid viscosity and pipe length.
  • ②Definirea variabilelor: $Q$ is volumetric flow rate ($\text{m}^3/\text{s}$), $r$ is internal pipe radius, $\Delta p$ is driving pressure drop, $\eta$ is dynamic viscosity ($\text{Pa}\cdot\text{s}$), and $L$ is pipe length.
  • ③Semnificație fundamentală: The cornerstone equation of microfluidics and cardiovascular hemodynamics. Extreme sensitivity to radius: halving the lumen radius ($r \to 0.5r$) increases hydraulic resistance 16-fold and reduces flow to $1/16$.
  • ④Domeniu de validitate și aplicații: **Strictly valid only for incompressible Newtonian fluids in laminar regime**; turbulent flow shifts pressure loss closer to quadratic flow dependence. Explains hypertension induced by arterial stenosis, guides hypodermic needle sizing, and governs microchannel lab-on-a-chip architecture.
06 · Reynolds Number Reynolds Number (Flow Regime Criterion)
1883 · Osborne Reynolds (United Kingdom)
$$\mathrm{Re} = \frac{\rho v L}{\eta} = \frac{v L}{\nu}$$
  • ①Esență fizică: Dimensionless ratio of inertial forces to viscous shear forces in a fluid flow, serving as the fundamental criterion that distinguishes smooth, predictable laminar flow from chaotic, fluctuating turbulent flow.
  • ②Definirea variabilelor: $\mathrm{Re}$ is the dimensionless Reynolds number, $\rho$ is density, $v$ is characteristic velocity, $L$ is characteristic length scale (e.g., pipe diameter), $\eta$ is dynamic viscosity, and $\nu = \eta/\rho$ is kinematic viscosity.
  • ③Semnificație fundamentală: The core foundation of dynamic similarity in fluid mechanics, allowing scaled experimental wind tunnel models to accurately reproduce full-scale prototype aerodynamics.
  • ④Domeniu de validitate și aplicații: For circular pipe flow, critical Reynolds number $\mathrm{Re}_{\text{crit}} \approx 2300$ ($\mathrm{Re} < 2300$ laminar, $\mathrm{Re} > 4000$ fully turbulent). Applied in aircraft and bullet train wind tunnel scaling, towing tank ship model testing, and pipeline pumping power estimation.
07 · Navier-Stokes Equations Navier-Stokes Equations (N-S Equations)
1845 · Claude-Louis Navier / George Stokes
$$\rho \frac{\mathrm{D}\mathbf{v}}{\mathrm{D}t} = -\nabla p + \eta \nabla^2 \mathbf{v} + \mathbf{f}$$
  • ①Esență fizică: The continuum formulation of Newton's second law (conservation of momentum) for viscous Newtonian fluids; the convective material acceleration on the left balances pressure gradients, viscous shear diffusion, and body forces on the right.
  • ②Definirea variabilelor: $\rho$ is density, $\mathbf{v}$ is velocity vector field, $\mathrm{D}/\mathrm{D}t = \partial/\partial t + (\mathbf{v}\cdot\nabla)$ is the material derivative, $p$ is static pressure, $\eta$ is dynamic viscosity, and $\mathbf{f}$ is body force per unit volume (e.g., $\rho \mathbf{g}$).
  • ③Semnificație fundamentală: The constitutional governing equations of modern fluid mechanics and computational fluid dynamics (CFD). The mathematical existence and smoothness of 3D Navier-Stokes solutions remains a Millennium Prize Problem.
  • ④Domeniu de validitate și aplicații: Continuous Newtonian fluids. Applied in numerical weather prediction models, full-vehicle aerodynamic CFD simulations, Formula 1 ground-effect downforce optimization, and 3D pulsatile arterial hemodynamics.

2. Laws of Thermodynamics (6 Laws)

Thermodynamics establishes energy conservation, the irreversible directional arrow of time, the absolute zero limit, and theoretical thermodynamic engine efficiency bounds.

08 · Zeroth Law of Thermodynamics Thermal Equilibrium Transitivity
1931 · Ralph H. Fowler (United Kingdom)
$$T_A = T_B, \ T_B = T_C \implies T_A = T_C$$
  • ①Esență fizică: If two thermodynamic systems are each in thermal equilibrium with a third system, they are also in thermal equilibrium with each other; thermal equilibrium satisfies mathematical transitivity.
  • ②Definirea variabilelor: $T_A, T_B, T_C$ represent the state parameter "thermodynamic temperature". Systems in mutual thermal equilibrium share identical temperature values.
  • ③Semnificație fundamentală: Axiomatically validates temperature as a well-defined scalar state function, providing the sole logical justification for thermometry.
  • ④Domeniu de validitate și aplicații: Universally valid for macroscopic states of thermal equilibrium. Applied in calibrating contact temperature sensors (mercury thermometers, thermocouples, resistance temperature detectors RTD) and establishing international temperature scales (ITS-90).
09 · First Law of Thermodynamics Conservation of Energy & Internal Energy
1847 · Joule / Helmholtz / Clausius
$$\Delta U = Q + W \iff \mathrm{d}U = \delta Q + \delta W$$
  • ①Esență fizică: The law of conservation and transformation of energy applied to thermodynamic systems; the change in internal energy equals the heat added to the system plus the work done on the system.
  • ②Definirea variabilelor: $\Delta U$ is change in internal energy ($\text{J}$), $Q$ is net heat absorbed (exothermic is negative), and $W$ is work performed on the system (for expansion work done by system, $\delta W = -p\mathrm{d}V$).
  • ③Semnificație fundamentală: The fundamental balance sheet of thermodynamic machinery. Internal energy $U$ is a state function (an exact differential $\mathrm{d}U$), whereas heat $Q$ and work $W$ are path-dependent inexact differentials ($\delta$).
  • ④Domeniu de validitate și aplicații: Universally holds for all closed and isolated systems. **Strictly disproves perpetual motion machines of the first kind** (machines that produce net work without energy input). Applied in internal combustion engine power stroke modeling, power plant boiler thermal balance, and refrigeration compressor sizing.
10 · Second Law of Thermodynamics Entropy Increase Principle
1824 Carnot / 1850 Clausius / Kelvin
$$\Delta S_{\text{isolated}} \ge 0 \iff \mathrm{d}S \ge \frac{\delta Q}{T}$$
  • ①Esență fizică: All spontaneous real macroscopic thermodynamic processes are irreversible; heat cannot spontaneously flow from a colder to a warmer body without external intervention. The total entropy of an isolated system never decreases.
  • ②Definirea variabilelor: $S$ is entropy ($\text{J/K}$), equality holds for idealized reversible processes, strict inequality applies to real irreversible processes, and $\delta Q/T$ is Clausius heat-temperature quotient.
  • ③Semnificație fundamentală: Defines the forward "arrow of time" in physical nature, sets theoretical limits on converting heat into mechanical work, and **rules out perpetual motion machines of the second kind**.
  • ④Domeniu de validitate și aplicații: Macroscopic multi-particle statistical ensembles. Applied in exergy availability loss analysis, Gibbs free energy spontaneity criteria ($\Delta G = \Delta H - T\Delta S < 0$), and industrial friction energy waste diagnostics.
11 · Third Law of Thermodynamics Nernst Heat Theorem
1906 · Walther Nernst (Germany)
$$S \to 0 \ (T \to 0\text{ K})$$
  • ①Esență fizică: As the thermodynamic temperature of a system approaches absolute zero ($0\;\text{K} = -273.15\;^\circ\text{C}$), the entropy of any pure, perfectly crystalline substance in ground state approaches zero; absolute zero cannot be attained in a finite sequence of operations.
  • ②Definirea variabilelor: $S$ is thermodynamic entropy ($\text{J/K}$), and $T$ is absolute temperature ($\text{K}$). At absolute zero, the ground state becomes non-degenerate ($W = 1$, $\ln W = 0$).
  • ③Semnificație fundamentală: Fixes the absolute reference baseline of entropy, enabling calculation of standard absolute entropies for chemical reactions.
  • ④Domeniu de validitate și aplicații: Perfect crystalline equilibrium ground states. Near absolute zero, isobaric heat capacity and thermal expansion coefficients vanish. Applied in superconducting magnet cryogenic cooling, helium dilution refrigeration limits, and quantum computing cryostats.
12 · Statistical Interpretation of Entropy Boltzmann's Entropy Formula
1877 · Ludwig Boltzmann (Austria)
$$S = k_B \ln W$$
  • ①Esență fizică: The entropy of a macroscopic state is proportional to the natural logarithm of the number of accessible microscopic states (thermodynamic probability $W$); entropy is a quantitative measure of micro-state multiplicity and statistical disorder.
  • ②Definirea variabilelor: $S$ is Boltzmann entropy, $k_B \approx 1.380649 \times 10^{-23}\;\text{J/K}$ is Boltzmann's constant, and $W$ (or $\Omega$) is the total count of microstates consistent with the macrostate.
  • ③Semnificație fundamentală: The great bridge linking macroscopic phenomenological thermodynamics to microscopic molecular statistical mechanics; reveals that irreversible entropy increase is simply a statistical progression from less probable to overwhelmingly probable configurations.
  • ④Domeniu de validitate și aplicații: Microcanonical ensembles and statistical equilibrium systems. Inscribed on Boltzmann's tombstone in Vienna. Formed the mathematical foundation for Shannon's information entropy, rubber elasticity conformational models, and nanoscale thermal physics.
13 · Carnot Efficiency Carnot Cycle Maximum Efficiency
1824 · Nicolas Léonard Sadi Carnot (France)
$$\eta = 1 - \frac{T_c}{T_h}$$
  • ①Esență fizică: All reversible heat engines operating between a high-temperature heat reservoir $T_h$ and a low-temperature cold reservoir $T_c$ attain the theoretical physical maximum thermal efficiency; no real irreversible cycle can exceed this upper bound.
  • ②Definirea variabilelor: $\eta$ is thermal efficiency, $T_h$ is hot reservoir thermodynamic temperature ($\text{K}$), and $T_c$ is cold sink thermodynamic temperature ($\text{K}$, strictly in Kelvin).
  • ③Semnificație fundamentală: The "speed-of-light limit" of heat engine engineering, dictating that improving power plant cycle efficiency requires **maximizing peak heat addition temperature $T_h$ and minimizing heat rejection temperature $T_c$**.
  • ④Domeniu de validitate și aplicații: Idealized closed reversible cycle consisting of two isothermal and two adiabatic stages. Applied in ultra-supercritical boiler steam power cycle optimization, aerospace gas turbine single-crystal blade cooling limits, and nuclear power plant condenser design.

3. Kinetic Theory & Statistical Physics (4 Laws)

Kinetic theory models macroscopic gas properties—pressure, temperature, transport, and equipartition—from statistical molecular collision dynamics and velocity distributions.

14 · Ideal Gas Law Ideal Gas Equation of State
1834 · Émile Clapeyron (France)
$$pV = nRT = N k_B T$$
  • ①Esență fizică: Unifies Boyle's, Charles's, Gay-Lussac's, and Avogadro's laws into a unified equation of state, defining the mathematical relation among pressure, volume, and temperature for dilute gases in equilibrium.
  • ②Definirea variabilelor: $p$ is pressure ($\text{Pa}$), $V$ is volume ($\text{m}^3$), $n$ is amount of substance ($\text{mol}$), $R \approx 8.314\;\text{J/(mol}\cdot\text{K)}$ is universal gas constant, $N$ is total molecular count, $k_B$ is Boltzmann's constant, and $T$ is absolute temperature ($\text{K}$).
  • ③Semnificație fundamentală: Baseline equation for gas behavior, derived from microscopic kinetic theory via $p = \frac{1}{3}nm\overline{v^2}$ and mean kinetic energy $\frac{1}{2}m\overline{v^2} = \frac{3}{2}k_B T$.
  • ④Domeniu de validitate și aplicații: Dilute gases at high temperature and low pressure where molecular volume and intermolecular potentials are negligible; dense or cold regimes require the van der Waals equation $[p + a(n/V)^2](V - nb) = nRT$. Applied in compressed gas cylinders, gas thermometers, and barometric altimetry.
15 · Boltzmann Distribution Maxwell-Boltzmann State Statistics
1877 · Ludwig Boltzmann (Austria)
$$N \propto e^{-E / k_B T} \iff P(E) = \frac{1}{Z}e^{-E / k_B T}$$
  • ①Esență fizică: In a classical particle system in thermal equilibrium, the probability of a state with energy $E$ being occupied is proportional to the Boltzmann factor $e^{-E / k_B T}$; occupation probability decays exponentially with energy, while higher temperatures broaden high-energy occupancies.
  • ②Definirea variabilelor: $P(E)$ is probability of microstate occupancy, $E$ is microstate energy, $k_B$ is Boltzmann's constant, $T$ is temperature, and $Z = \sum e^{-E_i / k_B T}$ is canonical partition function.
  • ③Semnificație fundamentală: The core postulate of equilibrium statistical physics, generating all macroscopic thermodynamic potentials from microscopic energy states.
  • ④Domeniu de validitate și aplicații: Distinguishable particles and weakly degenerate classical systems. Applied in chemical kinetics Arrhenius activation energy ($k \propto e^{-E_a/RT}$), semiconductor thermal carrier generation, barometric density decay with altitude, and simulated annealing algorithms.
16 · Maxwell-Boltzmann Speed Distribution Molecular Velocity Distribution
1860 · James Clerk Maxwell (United Kingdom)
$$f(v) = 4\pi\left(\frac{m}{2\pi k_B T}\right)^{3/2} v^2 e^{-mv^2 / 2k_B T}$$
  • ①Esență fizică: Gas molecules in equilibrium possess isotropic thermal velocity vectors; the probability density of finding a molecule with speed in $[v, v+\mathrm{d}v]$ is given by an asymmetric skewed bell curve, where $v^2$ stems from the 3D spherical velocity volume element $4\pi v^2\mathrm{d}v$.
  • ②Definirea variabilelor: $f(v)$ is speed probability density function, $m$ is single molecular mass, $v$ is molecular speed, $k_B$ is Boltzmann constant, and $T$ is absolute temperature.
  • ③Semnificație fundamentală: The first statistical distribution in physics describing microscopic velocity kinematics. The characteristic speeds satisfy: **most probable speed $v_p = \sqrt{2k_B T/m}$ < mean speed $\overline{v} = \sqrt{8k_B T/(\pi m)}$ < root-mean-square speed $v_{\text{rms}} = \sqrt{3k_B T/m}$**.
  • ④Domeniu de validitate și aplicații: Classical equilibrium ideal gases. Explains why liquids evaporate below their boiling points (high-kinetic-energy tail molecules overcome surface potential barriers), applied in gas isotope centrifugal separation and molecular beam epitaxy.
17 · Mean Free Path Mean Free Path
1859 · Rudolf Clausius (Germany)
$$\lambda = \frac{1}{\sqrt{2}\pi d^2 n} = \frac{k_B T}{\sqrt{2}\pi d^2 p}$$
  • ①Esență fizică: The average distance traversed by a gas molecule between successive elastic collisions with neighboring molecules; the factor $\sqrt{2}$ accounts for relative velocity between simultaneously moving colliding partners.
  • ②Definirea variabilelor: $\lambda$ is mean free path ($\text{m}$), $d$ is effective collision diameter ($\sim 10^{-10}\;\text{m}$), $n$ is molecular number density, $p$ is gas pressure, and $T$ is temperature.
  • ③Semnificație fundamentală: Microscopic physical yardstick for gas transport phenomena (viscosity, thermal conduction, mass diffusion); dictates whether flow operates in continuum ($\text{Kn} < 0.01$) or free molecular regime ($\text{Kn} > 10$).
  • ④Domeniu de validitate și aplicații: Hard-sphere elastic scattering. At standard ambient conditions, air molecules have $\lambda \approx 68\;\text{nm}$; under ultra-high vacuum ($p < 10^{-4}\;\text{Pa}$), $\lambda$ reaches kilometers, colliding primarily with chamber walls. Applied in semiconductor PVD/CVD deposition chamber vacuum calibration and vacuum insulation panel design.

4. Thermal Radiation & Heat Transfer (4 Laws)

Thermal energy transfers through conduction, convection, and electromagnetic radiation, governing industrial heat exchangers, cooling systems, and interstellar radiation.

18 · Stefan-Boltzmann Law Total Blackbody Emissive Power
1879 Stefan / 1884 Boltzmann
$$j = \sigma T^4 \quad (j = \varepsilon \sigma T^4)$$
  • ①Esență fizică: Total electromagnetic radiation power emitted per unit surface area into hemispherical space by a blackbody over all wavelengths (radiant emittance) is strictly proportional to the fourth power of its absolute thermodynamic temperature ($T^4$).
  • ②Definirea variabilelor: $j$ is radiant emittance ($\text{W/m}^2$), $\sigma = 2\pi^5 k_B^4 / (15c^2 h^3) \approx 5.670374 \times 10^{-8}\;\text{W/(m}^2\cdot\text{K}^4)$ is the Stefan-Boltzmann constant, $T$ is temperature ($\text{K}$), and $\varepsilon$ is real surface emissivity ($0 < \varepsilon < 1$).
  • ③Semnificație fundamentală: Macroscopic radiation law derived by integrating Planck's spectral distribution, demonstrating the steep $T^4$ non-linear growth in radiative emission.
  • ④Domeniu de validitate și aplicații: Diffuse emitting surfaces in thermal equilibrium. Applied in determining stellar radii from luminosity and temperature ($L = 4\pi R^2 \sigma T^4$), optical infrared pyrometer calibration, and space radiator sizing in deep-space cryogenic environments.
19 · Wien's Displacement Law Wien's Peak Emission Law
1893 · Wilhelm Wien (Germany)
$$\lambda_{\max} T = b \quad (b \approx 2.898\times 10^{-3}\text{ m}\cdot\text{K})$$
  • ①Esență fizică: The wavelength $\lambda_{\max}$ at which blackbody spectral radiance attains its maximum is inversely proportional to absolute temperature; peak emission shifts toward shorter wavelengths (higher frequencies) as temperature rises.
  • ②Definirea variabilelor: $\lambda_{\max}$ is peak emission wavelength ($\text{m}$), $T$ is absolute temperature ($\text{K}$), and $b \approx 2.89777 \times 10^{-3}\;\text{m}\cdot\text{K}$ is Wien's displacement constant.
  • ③Semnificație fundamentală: Established optical pyrometry and color temperature estimation from thermal spectra, providing a historical empirical catalyst for Planck's quantum hypothesis.
  • ④Domeniu de validitate și aplicații: Blackbody emission maxima. Explains color progression of heated metal from dull red to bright orange to white-hot; the Sun ($T \approx 5778\;\text{K}$) peaks in visible green light ($\sim 500\;\text{nm}$); human body ($310\;\text{K}$) peaks around $9.3\;\mu\text{m}$ mid-infrared, motivating pyroelectric infrared motion sensors.
20 · Fourier's Law of Heat Conduction Fourier's Law
1822 · Joseph Fourier (France)
$$\mathbf{q} = -k \nabla T \iff q = -k \frac{\mathrm{d}T}{\mathrm{d}x}$$
  • ①Esență fizică: In pure thermal conduction within an isotropic continuum, the local heat flux vector is proportional to the negative spatial temperature gradient; heat spontaneously flows down temperature gradients from hotter to colder regions.
  • ②Definirea variabilelor: $\mathbf{q}$ is heat flux density ($\text{W/m}^2$), $k$ (or $\lambda$) is thermal conductivity ($\text{W/(m}\cdot\text{K)}$), and $\nabla T$ is temperature gradient vector.
  • ③Semnificație fundamentală: The constitutive governing equation for conductive heat transfer; combining with internal energy conservation yields the transient heat diffusion equation $\partial T/\partial t = \alpha \nabla^2 T$ (where $\alpha = k/(\rho c_p)$ is thermal diffusivity).
  • ④Domeniu de validitate și aplicații: Dense solids and quiescent fluids. Applied in architectural thermal insulation design, CPU heat pipe and vapor chamber conduction modeling, and geothermal energy thermal depletion analysis.
21 · Newton's Law of Cooling Convective Heat Transfer
1701 · Sir Isaac Newton (United Kingdom)
$$\frac{\mathrm{d}T}{\mathrm{d}t} = -h(T - T_a) \iff T(t) = T_a + (T_0 - T_a)e^{-ht}$$
  • ①Esență fizică: When temperature difference between a surface and ambient flowing fluid is moderate, surface heat loss rate (convective flux $q = h_c(T_s - T_a)$) is proportional to temperature differential, yielding negative exponential thermal decay.
  • ②Definirea variabilelor: $T$ is instantaneous body temperature, $T_a$ is ambient medium temperature, $T_0$ is initial temperature, $h$ is overall cooling rate parameter ($\text{s}^{-1}$), and $t$ is elapsed time.
  • ③Semnificație fundamentală: Fundamental phenomenological model for convective heat transfer, showing rapid early cooling that asymptotically approaches ambient temperature.
  • ④Domeniu de validitate și aplicații: Small-to-moderate temperature differences dominated by convection; high temperatures or vacuum require $T^4$ radiative adjustments. Applied in industrial metal casting quench control, blast chilling time estimation, forensic postmortem time of death estimation, and electronics heatsink air cooling analysis.

5. Physical Quantities, Symbols, and SI Units

Physical Quantity Symbol Scalar / Vector SI Base or Derived Unit SI Symbol Equivalence & Conversions
Pressure / Stress $p, P$ Scalar (Pressure) / Tensor (Stress) Pascal Pa $1;\text{Pa} = 1;\text{N/m}^2 = 10^{-5};\text{bar} = 1/101325;\text{atm}$
Thermodynamic Temperature $T$ Scalar Kelvin (SI Base Unit) K $T(\text{K}) = t(^\circ\text{C}) + 273.15$
Celsius Temperature $t, \theta$ Scalar Degree Celsius °C $1;^\circ\text{C}$ temperature difference $\equiv 1;\text{K}$ difference
Heat / Internal Energy / Work $Q, U, W$ Scalar Joule J $1;\text{J} = 1;\text{N}\cdot\text{m} = 1;\text{W}\cdot\text{s} \approx 0.239;\text{cal}$
Thermodynamic Entropy $S$ Scalar Joules per Kelvin J/K $S = \int(\delta Q/T)$
Dynamic Viscosity $\eta, \mu$ Scalar Pascal-second $\text{Pa}\cdot\text{s}$ $1;\text{Pa}\cdot\text{s} = 1;\text{N}\cdot\text{s/m}^2 = 10;\text{P} = 1000;\text{cP}$
Kinematic Viscosity $\nu$ Scalar Square meters per second $\text{m}^2/\text{s}$ $1;\text{m}^2/\text{s} = 10^4;\text{St} = 10^6;\text{cSt}$
Volumetric Flow Rate $Q, \dot{V}$ Scalar Cubic meters per second $\text{m}^3/\text{s}$ $1;\text{m}^3/\text{s} = 1000;\text{L/s} = 3600;\text{m}^3/\text{h}$
Mass Flow Rate $\dot{m}$ Scalar Kilograms per second kg/s $\dot{m} = \rho \cdot Q$
Thermal Conductivity $k, \lambda$ Scalar Watts per meter-Kelvin $\text{W/(m}\cdot\text{K)}$ Silver $\sim 429$, Copper $\sim 400$, Water $\sim 0.6$, Air $\sim 0.026$
Heat Transfer Coefficient $h, \alpha$ Scalar Watts per square meter-Kelvin $\text{W/(m}^2\cdot\text{K)}$ Air free convection $5\text{--}25$, Water forced $1000\text{--}15000$
Radiant Emittance / Heat Flux $j, q$ Scalar (Emittance) / Vector (Flux) Watts per square meter $\text{W/m}^2$ $1;\text{W/m}^2 = 1;\text{J/(s}\cdot\text{m}^2)$
Boltzmann Constant $k_B$ Physical Constant Joules per Kelvin J/K $k_B = 1.380649 \times 10^{-23};\text{J/K}$ (exact)
Universal Gas Constant $R$ Physical Constant Joules per mole-Kelvin $\text{J/(mol}\cdot\text{K)}$ $R = N_A k_B \approx 8.314462;\text{J/(mol}\cdot\text{K)}$
Stefan-Boltzmann Constant $\sigma$ Physical Constant Watts per square meter-Kelvin$^4$ $\text{W/(m}^2\cdot\text{K}^4)$ $\sigma \approx 5.670374 \times 10^{-8};\text{W/(m}^2\cdot\text{K}^4)$
Wien Displacement Constant $b$ Physical Constant Meter-Kelvin $\text{m}\cdot\text{K}$ $b \approx 2.897772 \times 10^{-3};\text{m}\cdot\text{K}$
Reynolds Number $\mathrm{Re}$ Dimensionless Dimensionless (1) - $\mathrm{Re} = \rho v L / \eta$ (inertial force / viscous force)

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